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Ferrinatrite R170042



Name: Ferrinatrite
RRUFF ID: R170042
Ideal Chemistry: Na3Fe3+(SO4)3·3H2O
Locality: Alcaparrosa, Antofogasta, Chile
Source: James Shigley
Owner: RRUFF
Description: Colorless acicular crystals, associated with colorless tabular rhomboclase (R070507) and pale yellow-brown römerite
Status: The identification of this mineral has been confirmed by single-crystal X-ray diffraction.
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented Raman on the primary sample
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R170042
Wavelength:
Sample Description: Unoriented Raman on the primary sample
Instrument settings: none 532nm @ 100% of mW
POWDER DIFFRACTION 
RRUFF ID: R170042.9
Sample Description: Single crystal, powder profile is calculated
Cell Refinement Output: a: 15.5762(30)Å    b: 15.5762(30)Å    c: 8.6657(11)Å
alpha: 90°    beta: 90°    gamma: 120°   Volume: 1820.77(59)Å3    Crystal System: hexagonal
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REFERENCES for Ferrinatrite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Mackintosh J B (1889) Notes on some native iron sulphates from Chili, American Journal of Science, 38, 242-245   [view file]

Cesbron F (1964) Contribution à la minéralogie des sulphates de fer hydratés, Bulletin de la Société Française de Minéralogie et de Cristallographie, 87, 125-143   [view file]

Scordari F (1977) The crystal structure of ferrinatrite, Na3(H2O)3[Fe(SO4)3] and its relationship to Maus's salt, (H3O)2K2{K0.5(H2O)0.5}6[Fe3O(H2O)3(SO4)6](OH)2, Mineralogical Magazine, 41, 375-383   [view file]

Ventruti G, Della Ventura G, Lacalamita M, Sbroscia M, Sodo A, Plaisier J R, Cinque G, Schingaro E (2019) Crystal-chemistry and vibrational spectroscopy of ferrinatrite, Na3[Fe(SO4)3]·3H2O, and its high-temperature decomposition, Physics and Chemistry of Minerals, 46, 119-131

Yang Z, Giester G (2019) Structure refinement and hydrogen bonding of ferrinatrite, Na3Fe(SO4)3·3H2O, Mineralogy and Petrology, 113, 555-562   [view file]